Chemistry: fischer-tropsch processes; or purification or recover – Group ib metal containing catalyst utilized for the...
Patent
1993-10-27
1994-11-15
Mars, Howard T.
Chemistry: fischer-tropsch processes; or purification or recover
Group ib metal containing catalyst utilized for the...
518728, C07C 2706
Patent
active
053648870
ABSTRACT:
Methanol is catalytically produced from a synthesis gas which contains H.sub.2, CO and CO.sub.2 in a synthesis reactor at temperatures from 220.degree. to 300.degree. C. and under a pressure in the range from 20 to 120 bars. A product mixture which contains methyl formate is withdrawn from the synthesis reactor and is cooled to temperatures in the range from 20.degree. to 60.degree. to provide a condensate which contains methanol, water and methylformate. A gas mixture which contains H.sub.2, CO and CO.sub.2 is formed at the same time. A fraction which comprises 10 to 100% by weight methyl formate is separated from the condensate and is admixed with the synthesis gas which is fed to the synthesis reactor.
REFERENCES:
patent: 3920717 (1975-11-01), Marion
patent: 3962300 (1976-06-01), Hiller et al.
patent: 4348486 (1982-09-01), Calvin et al.
Ullmann's Encyclopedia of Industrial Chemistry, vol. A 16, pp. 469-475.
Konig Peter
Moller Friedrich-Wilhelm
Supp Emil
Mars Howard T.
Metallgesellschaft Aktiengesellschaft
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