Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof
Reexamination Certificate
2008-04-22
2008-04-22
Puttlitz, Karl (Department: 1621)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From carboxylic acid or derivative thereof
C526S317100, C560S216000
Reexamination Certificate
active
11129479
ABSTRACT:
In this invention, a process of thermal degradation of biodegradable bacterial polyesters poly(hydroxyalkanoate)s (PHAs) to lower molecular weight PHAs in controllable manner has been developed. The process involves using at least one additional component to ‘dilute’ the PHAs in the thermal degradation process, so that the process can be controlled in the senses of better heat transfer, better stirring, easier working up after the reaction. The relationship of processing time and the molecular weights of the products at a certain temperature was obtained so that it is possible to obtain the desired molecular weight products in the real production under the guidance of the relationship.
REFERENCES:
patent: 5191016 (1993-03-01), Yalpani
patent: 5268422 (1993-12-01), Yalpani
patent: 5665831 (1997-09-01), Neuenschwander et al.
patent: 6534599 (2003-03-01), Marchessault et al.
Lehrle et al., Thermal Degradation of Bacterial Poly(hydroxybutyric acid): Mechanisms from the Dependence of Pyrolysis Yields on Sample Thickness, Macromolecules, 1994, 27, 3782-3789.
N. Grassie et al, “The Thermal Degradation of Poly((D)-.beta.-Hydroxybutyric Acid): Part 1-Ident. & Quant. Analysis of Products”, Elsevier, Eng., 1984, pp. 47-61.
N. Grassie et al, “The Thermal Degradation of Poly(-(D)-.beta.-Hydroxybutyric Acid: Part 2-Changes in Molecular Weight”, Elsevier, Eng., 1984, pp. 96-103.
N. Grassie et al, “The Thermal Degradation of Poly(-(D)-.beta.-Hydroxybutyric Acid): Part 3-The Reaction Mechanism”, Elsevier, Eng., 1984, pp. 127-134.
M. Kunioka et al, “Thermal Degradation of Microbial Copolyesters . . . ”, American Chemical Society, 1990, pp. 89-92.
S. Coulombe et al, “High Pressure Liquid Chromatography . . . ” Macromolecules, 11, pp. 279-280 (1978).
H. Morikawa et al, “Pyrolysis of Bacterial Polyalkanoates”, Can. J. Chem., 59, pp. 2306-2313 (1981).
G.E. Yu et al, “Characterisation of low molecular weight . . . ”, Polymer, 2000, 41, 1087-1098.
S. Nguyen et al, “Thermal Degradation of Poly(3-hydroxyalkanoates) . . . ”, Biomacromolecules, 2002, 3(1), 219.
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