Process of producing ethylbenzene using alkylation and transalky

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585323, 585449, 585470, 585483, C07C 100, C07C 264, C07C 522, C07C 412

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059627581

ABSTRACT:
Ethylbenzene is produced from benzene and ethylene in an alkylation reactor wherein the feedstocks also contain propylbenzenes and/or components that produce propylbenzene. Polyethylbenzenes are also produced in the process. The ethylbenzene product and unreacted benzene are separated and then the propylbenzenes are separated from the polyethylbenzenes by distillation. The propylbenzenes are destroyed in a vapor-phase reactor and the polyethylbenzenes are transalkylated with benzene in a liquid or partial liquid phase at a lower temperature.

REFERENCES:
patent: 4320242 (1982-03-01), Odonera et al.
patent: 5030786 (1991-07-01), Shamshoum et al.
patent: 5476978 (1995-12-01), Smith, Jr. et al.
patent: 5689025 (1997-11-01), Abichandani et al.

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