Process of pressureless sintering to produce dense, high thermal

Plastic and nonmetallic article shaping or treating: processes – Including step of generating heat by friction

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264 61, 423412, 501 96, 501 98, C04B 3558

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044787855

ABSTRACT:
The process comprises forming a mixture comprised of aluminum nitride powder and free carbon wherein the aluminum nitride has a predetermined oxygen content higher than about 0.8% by weight and wherein the amount of free carbon reacts with such oxygen content to produce a deoxidized powder or compact having an oxygen content ranging from greater than about 0.35% by weight to about 1.1% by weight and which is at least 20% by weight lower than the predetermined oxygen content, heating the mixture or a compact thereof to react the carbon and oxygen producing the deoxidized aluminum nitride, and sintering a compact of the deoxidized aluminum nitride producing a ceramic body having a density greater than 85% of theoretical and a thermal conductivity greater than 0.5 W/cm.K at 22.degree. C.

REFERENCES:
patent: 3108887 (1963-10-01), Lenie et al.
patent: 3718490 (1973-02-01), Morgan et al.
patent: 4203733 (1980-05-01), Tanaka et al.
patent: 4435513 (1984-08-01), Komeya et al.
Chem. Abstracts, vol. 99. (Jul. 25, 1983) p. 274, Abstr. No. 26975r.

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