Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1983-08-23
1985-10-08
Garvin, Patrick P.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
502115, 502121, 502123, 502124, 502125, 502126, 502127, 526125, C08F 464
Patent
active
045460922
ABSTRACT:
A process is disclosed for preparing a titanium catalyst component useful for homopolymerizing 1-alkenes and for copolymerizing 1-alkenes with each other and/or with ethylene, consisting essentially in grinding a titanium halide compound/electron-donor complex with a magnesium aluminum halide obtained by precipitation from an organic solvent.
In the process the ground product is first washed with a washing liquid containing a solvent for the aluminum halide/electron-donor complex which forms during the grinding process and by preference at least one alcohol, the molar ratio between alcohol and titanium in the ground product ranging between 50:1 and 1:20, and then the washed product is exposed to a liquid titanium halide compound.
With this procedure, it is possible to obtain a titanium component which imparts to the polymerization catalyst an excellent stereospecificity along with a very high activity, and with which it is possible to obtain polymers, e.g. polypropylene, with a very low halogen content, a very low titanium content, and an excellent powder morphology and bulk density.
Loontjens Jacobus A.
Muskens Bernardus J.
Garvin Patrick P.
Stamicarbon B.V., Licensing Subsidiary of DSM
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