Process of polymerizing chloroetrifluoroethylene with alkyl hydr

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526249, C08F 440

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active

054534771

ABSTRACT:
Process for the production of PCTFE homopolymer and/or copolymer resins by the use of an aqueous suspension system incorporating a redox initiator system which comprises t-butyl hydroperoxide and sodium metabisulfite to initiate the polymerization or copolymerization process. The process parameters may be controlled to provide a PCTFE homopolymer or copolymer resin having a desired target range of molecular weights. The process provides stable PCTFE polymer suspensions which exhibit a low tendency to coagulate and further exhibit good wettability of the homopolymer and copolymer particles, notably in the absence of soaps.

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3"Chlorotrifluoroethylene Polymers", Science & Engineering, 463, 476 (2nd Ed. 1985).

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