Process of making oxygen enriched plutonium dioxide (PuO.sub.2)

Chemistry of inorganic compounds – Radioactive – Transuranium compound

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2523011R, 264 5, C01G 5600, C09K 300

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active

040426700

ABSTRACT:
Process for enriching .sup.238 PuO.sub.2 with .sup.16 O and forming sintered fuel pellets therefrom comprising the steps of compressing a mass of .sup.238 PuO.sub.2 containing .sup.16 O, .sup.17 O and .sup.18 O into a pellet; exposing the pellet to an atmosphere of .sup.16 O and an inert carrier gas at an increasing temperature up to about 1400.degree. C with varied gas flow to obtain an exchange of .sup.17 O and .sup.18 O and the simultaneous sintering of the pellet; and cooling the sintered and exchanged pellet.

REFERENCES:
patent: 3420640 (1969-01-01), Porter
patent: 3515875 (1970-06-01), Keshishian
patent: 3520819 (1970-07-01), Litherland et al.
patent: 3666846 (1972-05-01), Sump et al.
patent: 3677958 (1972-07-01), Lonadier et al.
Plymale (1), The Exchange of Isotopically Enriched Oxygen With .sup.238 PuO.sub.2 Sol-Gel Microspheres, U.S. At. Energy Comm., 1968, MLM-1462 8 pages.
Plymale (2), J. Inorgan. Nucl. Chem., 1968, vol. 30, No. 3, pp. 886-890.

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