Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1977-02-01
1978-06-06
Davis, C.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2606533, C07C 2118
Patent
active
040936708
ABSTRACT:
Easy-to-prepare dimers of hexafluoropropene such as ##STR1## are heated at 20.degree.-150.degree. C in a nonprotonic polar solvent such as acetonitrile in the presence of an alkali metal fluoride and a crown ether to isomerize the dimers into thermodynamically stable ##STR2## This process is applicable also to the isomerization of trimers such as ##STR3##
REFERENCES:
ishikawa et al. (I), Chemical Abstracts; 78, 57656h.
Ishikawa et al. (II), Chemical Abstracts, 83, 163550g.
Martini et al., Tetrahedron Letters No. 24, pp. 2129-2132, 1974.
Komatsu Tadaaki
Matsuoka Kimiaki
Ozawa Masahiro
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