Process of hydrogenating benzenes and group IVa metal hydride ca

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Using transition metal-containing catalyst

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585266, C07C 502, C07C 503

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044094116

ABSTRACT:
Benzene, or an alkylbenzene, is hydrogenated by reaction with hydrogen in the presence of a Group IVa (titanium family) or Va metal hydride catalyst. The catalyst may be a simple hydride such as ZrH.sub.2 or a hydride of an alloy such as Cu.sub.3 Zr or may be a complex material. One complex material is the reaction product of a Group IVa or Va metal halide, such as ZrCl.sub.4 with an alkyllithium or aryllithium, such as n-butyllithium, in a hydrocarbon solvent.

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