Process of directly imaging a thermosensitive polyacetylene salt

Radiation imagery chemistry: process – composition – or product th – Dye image from radiation sensitive dye or dye former by dry... – Composition or product

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430336, 430346, 430945, 430340, 524550, 526285, 548156, G03C 173, C08L 4900

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active

052328201

ABSTRACT:
This invention relates to novel thermochromic quaternized polyacetylene salt derivatives which are visually imageable by exposure to a light source generating energy in a wavelength of from about 400 nm to about 1500 nm said salt derivative having a thermosensitivity of at least 50.degree. C. and defined by the formula ##STR1## or a homopolymer thereof wherein X is the N-quaternized monovalent radical of a dye having an optical absorbance in a wavelength of from about 400 nm to about 1500 nm; V is the cationic residue of a carboxyl, sulfonate, thioate, thiolic, thionic or phosphonate radical; n has a value of from 2 to 4 and X' is hydrogen, C.sub.4 to C.sub.25 alkyl, a polar hydrophilic group which promotes hydrogen bonding containing a radical of the group of an amino, amido, hydroxy, ester, ether, phenol, carboxy, halo, sulfonyl, sulfoxy, sulfinyl, silyl, silyoxy, phosphoro, phosphate, keto, carbamate, aldehyde, urea, urethane, a metal salt group or X' is selected from the group defined for X.

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patent: 3844791 (1974-10-01), Bloom et al.
patent: 5004671 (1991-04-01), Nishimura et al.
patent: 5049428 (1991-09-01), Kanno et al.
patent: 5153106 (1992-10-01), Liu

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