Process of crosslinking unsaturated hydrocarbon polymers employi

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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260768R, 560 22, 560 25, 560 29, 560 30, 560 31, 560 32, 560 24, 560137, 560158, 560163, 560157, C08C 1912, C08C 1922, C08C 1928, C08J 324

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041600770

ABSTRACT:
A process for the cross-linking or chain extension of hycrocarbon polymers which contain ethylenically unsaturated groups which comprises forming an intimate mixture of the polymer with a carbamate of the formula: ##STR1## WHEREIN R.sub.1 is an optionally substituted hydrocarbyl radical, m is an integer, and A is H or an optionally substituted hydrocarbyl radical of valency m, and subjecting the mixture to heat.
Novel compounds of preferred use include those in which m=1 and at least one of R and A is alkyl or 7 or more carbon atoms, or in which m=2 and A is phenylene or alkylene or alkenylene of 2 to 4 carbon atoms.

REFERENCES:
patent: 3721659 (1973-03-01), Cain et al.
patent: 3904592 (1975-09-01), Sexsmith et al.
patent: 4073800 (1978-02-01), Brooks et al.

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