Process of controlled radical grafting of a polyolefin

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C525S192000, C525S193000, C525S194000

Reexamination Certificate

active

07544743

ABSTRACT:
The present invention relates to a controlled radical grafting process of a polyolefin derived from monomeric units including α-olefins. This process comprises the reaction of the polyolefin and at least one radical reaction initiator with a grafting system which comprises at least one grafting compound having an electron donator heterocyclic aromatic ring conjugated to at least one —HC═CR1R2group in which at least one of R1and R2is an electron acceptor functional group. The process can be performed continuously in an extruder or discontinuously in a mechanical mixer.

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patent: 5001197 (1991-03-01), Hendewerk
patent: 5712323 (1998-01-01), Braga et al.
patent: 6506863 (2003-01-01), Romani et al.
patent: 1 216 999 (2002-06-01), None
F. Romani, et al.: “Monitoring the Chemical Crosslinking of Prolylene Polymers Through Rheology”, Polymer, Elsevier Science Publishers B.V., GB, vol. 43, No. 4, Feb. 2002, pp. 1115-1131, XP004312430 ISSN: 0032-3861.
B. Wong, et al.: “Melt Rheology of Graft Modified Polypropylene” Polymer, Elsevier Science Publishers B.V., GB, vol. 38, No. 11, May 1997, pp. 2781-2789, XP004061851, ISSN: 0032-3861.

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