Process of bulk polymerization of styrene using azoalkane mixtur

Details Process of bulk polymerization of styrene using azoalkane mixtur Process of bulk polymerization of styrene using azoalkane mixtur

1988-01-21

1989-05-16

Higel, Floyd D.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

5253333, 525376, 525910, 525912, 5262181, 5262192, 526346, 526347, 5263472, 528396, 534573, 534587, 534838, 534886, 502167, C08F 404, C08F 1208, C07C10702

Patent

active

048310964

ABSTRACT:
Mixtures of azolakanes of varying thermal stabilities at least one of which is an unsymmetrical azoalkane (R--N.dbd.N--R'), are prepared by reacting 4 equivalents of a mixture of two or more primary alkyl, cycloalkyl or aralkylamines with 1 equivalent of sulfuryl chloride in an inert solvent and oxidizing the resulting mixture of sulfamide products with basic bleach. The unsymmetrical azoalkanes can be separated from the symmetrical azoalkanes by a variety of conventional techniques. The azoalkane mixtures are excellent polymerization initiators for vinyl monomers and curing agents for unsaturated polyester resins.

REFERENCES:
patent: 4007165 (1977-02-01), MacLeay et al.
patent: 4604455 (1986-08-01), MacLeay
Ohme et al., Justus Liebigs Ann. Chem., vol. 713, pp. 74 to 86 (1968).
Overberger et al., J. Amer. Chem. Soc., vol. 80, pp. 6562 to 6568 (1958).
Spialter et al., J. Org. Chem., vol. 30, pp. 3278 to 3283 (1965).
Timberlake et al., J. Org. Chem., vol. 41, pp. 1666 to 1667 (1968).
Engel et al., J. Am. Chem. Soc., vol. 97, pp. 6754 to 6762 (1975).
Ohme et al. Chemical Abstracts, vol. 63, 5515i d (1965).
Spialter et al., J. Org. Chem., vol. 30, pp. 3278 to 3283 (1965).
Ohme et al. Justus Liebigs Ann. Chem., vol. 713, pp. 74-86, (1968).
Overberger et al., J. Amer. Chem. Soc., vol. 80, pp. 6562-6568 (1958).
Timberlake et al., J. Org. Chem., vol. 41, pp. 1666-1667 (1968).

Affiliated with

Also associated with

Rating

Process of bulk polymerization of styrene using azoalkane mixtur does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process of bulk polymerization of styrene using azoalkane mixtur, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process of bulk polymerization of styrene using azoalkane mixtur will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2323347