Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – Clay
Patent
1993-01-29
1994-07-19
Dees, Carl F.
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
Clay
502 81, B01J 2012, B01J 2116, B01J 3700
Patent
active
053309464
ABSTRACT:
A bentonite clay-based polymerization catalyst is manufactured by adhering together a plurality of smaller acid-activated bentonite clay particles, using a strong mineral acid, such as H.sub.2 SO.sub.4, as a binder. An acid-activated bentonite clay having a particle size below about 60 mesh, U.S. Sieve Series, preferably calcium bentonite, having calcium as a predominant exchangeable action, is mixed with a strong mineral acid, preferably H.sub.2 SO.sub.4, and water to form the catalyst. The mixture is subjected to intensive mixing, curing and drying to form strong particles capable of grinding to a desired particle size distribution, e.g., -6 mesh to +60 mesh, U.S. Sieve Series, to form the catalyst. Fines resulting from the grinding step are completely recycled to the intensive mixing stage of the process to achieve 100% yield. Some adjustment of acid content of the mix may be needed to take into account the acid carried into the mix by recycled fines.
REFERENCES:
patent: 1544210 (1925-06-01), Bierce
patent: 2892800 (1959-06-01), Taipale
patent: 2981697 (1961-04-01), Mickelson et al.
patent: 4717699 (1988-01-01), Mickelson
Hynes Russell E.
Nebergall Robert S.
American Colloid Company
Dees Carl F.
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