Process for working up the waste water obtained in the...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S927000, C568S939000, C568S940000

Reexamination Certificate

active

06936741

ABSTRACT:
The present invention relates to a process for working up or treating aqueous waste waters which are formed during the nitration of toluene to dinitrotoluene with nitrating acid. These aqueous waste waters containing acidic wash water and alkaline wash water from the dinitrotoluene washing step, and distillate from the sulfuric acid concentration step. The process comprises,a) combining the acidic and alkaline waste waters from the washing step and the aqueous distillate from the sulfuric acid concentration step such that the resulting mixture has a pH below 5,b) separating the aqueous and organic phases which are formed by phase separation,c) subjecting the aqueous phase from b) to an extraction step, whereind) the organic components contained in the aqueous phase from c) are extracted with toluene, ande) introducing the toluene phase enriched with the organic components into the toluene nitration.

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patent: 6288289 (2001-09-01), Boyd et al.
patent: 6506948 (2003-01-01), Sawicki

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