Mineral oils: processes and products – Refining – Sulfur removal
Patent
1998-03-27
1999-05-18
Myers, Helane
Mineral oils: processes and products
Refining
Sulfur removal
208 27, 208230, 208208, 208258, 208259, C10G29/00
Patent
active
059048395
ABSTRACT:
The present invention relates to a continuous in-situ process for reducing the viscosity, corrosivity and density of heavy oils comprising the steps of (a) contacting a heavy oil with an anhydrous alkaline earth, Group IIA metal hydroxide and low pressure hydrogen at a temperature of about 380.degree. C. to about 450.degree. C. for a time sufficient to form the corresponding alkaline earth metal sulfide, recovering the reduced sulfur feed and regenerating the alkaline metal hydroxide for recycle to treat additional feed. Beneficially, the process removes heteroatoms (sulfur and nitrogen).
REFERENCES:
patent: 2795532 (1957-06-01), Honeycutt
patent: 3164545 (1965-01-01), Mattox
patent: 3440164 (1969-04-01), Aldridge
patent: 3449242 (1969-06-01), Mattox et al.
patent: 4003823 (1977-01-01), Baird, Jr. et al.
patent: 4007109 (1977-02-01), Baird, Jr. et al.
patent: 4033860 (1977-07-01), Carlson
patent: 4087348 (1978-05-01), Baird, Jr. et al.
patent: 4127470 (1978-11-01), Baird, Jr. et al.
patent: 4163043 (1979-07-01), Dezael et al.
patent: 4199440 (1980-04-01), Verachtert
patent: 4310049 (1982-01-01), Kalvinskas et al.
patent: 4437980 (1984-03-01), Heredy et al.
patent: 4566965 (1986-01-01), Olmstead
Kalichevsky and Kobe, Petroleum Refining With Chemicals, Ch. 4, Elsevier Publishing (1956).
LaCount, et al, "Oxidation of Dibenzothiophene and Reaction of Dibenzothiophene . . . ", J. Org. Chem., vol. 42, No. 16, pp. 2751-2754 (1977).
Burger, et al, "Symposium on Progress in Processing Synthetic Crudes and Resids", Atlantic Richfield Company, pp. 765-775 (8/24-29/95).
Exxon Research and Engineering Co.
Myers Helane
Scuorzo Linda M.
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