Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...
Patent
1987-06-01
1988-10-11
Garvin, Patrick P.
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By addition of entire unsaturated molecules, e.g.,...
585510, 585511, 585513, C07C 224
Patent
active
047773154
ABSTRACT:
A process for the trimerization of an olefin selected from the group consisting of ethylene, propylene, 1-butene, and mixtures thereof comprising passing the olefin and carbon dioxide in contact with a catalyst comprising the reaction product of (i) a chromium compound, which will provide active catalytic species under trimerization conditions, and (ii) a hydrocarbyl aluminum hydrolyzed with about 0.7 to about 1.1 moles of water per mole of aluminum compound wherein the aluminum to chromium mole ratio is in the range of up to about 200 to one and the mole ratio of olefin to carbon dioxide is in the range of about 4 to about 3000 moles of olefin per mole of carbon dioxide.
REFERENCES:
patent: 4528414 (1985-07-01), Long et al.
patent: 4668838 (1987-05-01), Briggs
Karol Frederick J.
Levine Isaac J.
Bresch Saul R.
Fourson George R.
Garvin Patrick P.
Union Carbide Corporation
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