Mineral oils: processes and products – Refining – Sweetening
Patent
1978-08-28
1980-05-20
Crasanakis, George
Mineral oils: processes and products
Refining
Sweetening
C10G 2706
Patent
active
042038278
ABSTRACT:
A process for treating a mercaptan-containing sour petroleum distillate is disclosed. A sour petroleum distillate, in admixture with an oxidizing agent, is passed into contact with a catalytic composite in the presence of an alkaline reagent, said catalytic composite comprising a metal chelate mercaptan oxidation catalyst and a quaternary ammonium compound impregnated on a solid adsorbent support disposed as a fixed bed in a first treating zone. The effluent from said first zone, in admixture with an oxidizing agent, is then passed into contact with a catalytic composite in the presence of an alkaline reagent, said catalytic composite comprising a metal chelate mercaptan oxidation catalyst impregnated on a solid adsorbent support disposed as a fixed bed in a second treating zone. A petroleum distillate, substantially free of mercaptan sulfur, is recovered from the second treating zone.
REFERENCES:
patent: 2744854 (1956-05-01), Urban, Jr.
patent: 3108081 (1963-10-01), Gleim et al.
patent: 4070271 (1978-01-01), Carlson et al.
Crasanakis George
Hoatson Jr. James R.
McBride Thomas K.
Page II William H.
UOP Inc.
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