Process for treating solutions containing tritiated water

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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Details

204149, 423249, 252630, C25B 102, C02F 146

Patent

active

044876700

ABSTRACT:
The invention relates to a process and to an apparatus for treating solutions containing tritiated water.
According to this process, an electrolyte such as soda is added to the solution, the solution obtained then undergoes electrolysis in order to release tritium in the gaseous state. Working takes place in an electrolytic cell having a cathode made from a metal which aids the diffusion of tritium, e.g. a Pd-Ag alloy coated with porous palladium black. The cathode forms a separating wall between the solution to be electrolyzed and a tritium reception compartment. The tritium which has diffused through the wall of the cathode is recovered in the compartment.
Use for the recovery of tritium from effluents resulting from the reprocessing of irradiated nuclear fuels.

REFERENCES:
patent: 2863526 (1960-11-01), Salmon
patent: 3620844 (1971-11-01), Wicke
patent: 4000048 (1976-12-01), Bianchi
patent: 4190507 (1980-02-01), Hesky
patent: 4225402 (1980-09-01), LeRoy
patent: 4331522 (1982-05-01), Pierini

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