Process for transhalogenating a halophosphorous compound with an

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters

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558140, 568 14, 568 16, C07F 914

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050496913

ABSTRACT:
Phosphorus compounds having at least one chlorine, bromine or iodine bonded directly to phosphorus are transhalogenated with fluorine by reaction with anhydrous hydrogen fluoride in an inert solvent, e.g., xylene, methylene chloride, in a manner such that said anhydrous hydrogen fluoride is added to said phosphorus compound at a rate such that said anhydrous hydrogen fluoride reacts with said phosphorus compound without the accumulation of an amount of unreacted anhydrous hydrogen fluoride which is sufficient to cause substantial decomposition of the desired fluorophosphorus product.

REFERENCES:
patent: 4929745 (1990-05-01), Kelbys et al.

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