Process for transforming hydrocarbon polymers into photodegradab

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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96 88, 96114, 526 41, 526 42, 526 52, 526 53, 526352, 526914, C08F 830

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039637913

ABSTRACT:
A hydrocarbon polymer, such as high density polyethylene, is rendered photodegradable through the introduction into the polymer chain of photosensitive >C= O groups by reacting the polymer with a compound such as NOCl in the heterogeneous phase in an acid environment so that - NO groups are introduced into the polymer chain which are converted into >N--OH groups and then subjecting the resultant polymer to hydrolysis so that the >N--OH groups are converted into photosensitive >C = O groups.

REFERENCES:
patent: 3583961 (1971-06-01), Magay
patent: 3723404 (1973-03-01), Davis et al.

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