Process for thermal decomposition of aluminum chloride hydrates

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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23262, 23277R, 23284, 34 10, 34 11, 423DIG16, 423481, 432 15, C01F 730

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040910857

ABSTRACT:
Thermal decomposition of aluminum chloride hydrate in a fluidized bed reactor in which the concentration of solids diminishes from the bottom upwards, the improvement wherein most of the hydrogen chloride is removed from the hydrate by direct heat and the largely decomposed aluminum chloride is fed into a calcining reactor and from the calcining reactor to a residence time reactor fluidized at low gas velocity, recycling solids from the residence reactor to the calcining reactor in an amount to adjust the suspension density and feeding the remainder to a cooler after sufficient time in the residence reactor.

REFERENCES:
patent: 2539263 (1951-01-01), Mumlay
patent: 2780525 (1957-02-01), Wendell et al.
patent: 3130008 (1964-04-01), Stokes et al.
patent: 3144303 (1964-08-01), Engelmann
patent: 3579616 (1971-05-01), Reh et al.
patent: 3648380 (1972-03-01), Goulloud
patent: 3754993 (1973-08-01), Oguchi et al.
patent: 3836635 (1974-09-01), Reh et al.
Reh, "Chemical Engineering Progress," vol. 67, 1971, pp. 58-63.

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