Specialized metallurgical processes – compositions for use therei – Processes – Producing or treating free metal
Reexamination Certificate
2000-02-18
2002-03-05
Andrews, Melvyn (Department: 1742)
Specialized metallurgical processes, compositions for use therei
Processes
Producing or treating free metal
C075S444000, C075S751000, C075S765000
Reexamination Certificate
active
06352572
ABSTRACT:
This invention relates to a process for the thermal treatment of granular, moist iron ore, where the ore is passed through a drying zone, and where the ore, which comes from the drying zone with a temperature in the range from 120 to 400° C., is heated in direct contact with hot gas to temperatures of 700 to 1100° C., before it is charged into a reduction zone.
Such processes are known and described for instance in the U.S. Pat. Nos. 5,527,379; 5,560,762; and 5,603,748. In this case, the thermal treatment serves the preparation of the ore for being charged into a reduction plant, which operates with one or more fluidized beds. As fluidizing gas, gas rich in hydrogen is used, which as a further reducing component may also contain carbon monoxide. It was found out that ore components with a particularly fine grain disturb the reduction process and reduce the quality of the product, because these fine-grained components are easily blown out of the fluidized bed. As a result, their dwell time in the reduction zone is reduced such that they are no longer reduced sufficiently.
It is the object underlying the invention to ensure that during the thermal pretreatment of the iron-containing ore or an ore concentrate the ore introduced into the reduction zone does not contain any disturbing amounts of fine grain. In accordance with the invention this object is solved in the above-mentioned process in that the ore coming from the drying zone is wholly or partly passed through a separating means, and a coarse-grained ore fraction is separated from a fined-grained ore fraction, that the fine-grained ore fraction is charged into a granulating means and an iron ore granulate is produced, which is introduced into the drying zone, and that the coarse-grained ore fraction is heated to temperatures of 700 to 1100° C., before it is introduced into the reduction zone. The separating means may for instance be a screen or a sifter.
Particularly fine-grained ore, which is undesired in the reduction plant, is obtained in several ways. On the one hand, fines are formed during the drying and heating of the granular ore, and there is also formed fine grain owing to the sputtering of coarser grains during heating. Furthermore, the crude ore, which is provided for the reduction in the fluidized bed, is crushed even before drying to the optimum grain size of about 0.1 to 3 mm. To this end, rolling presses known per se may be used for instance, but there is inevitably also produced ore with an extremely fine grain size. Screening and granulating this fine-grained component prior to drying, as it is proposed for instance in U.S. Pat. No. 5,560,762, does not completely solve the problem of fine grain, because fine grain is also formed again during drying and the thermal pretreatment as a result of abrasion and sputtering. By means of the process in accordance with the invention it is efficiently and economically ensured that no disturbing amounts of fine grain can get into the reduction plant.
It is usually provided that the ore coming from the drying zone is introduced into the separating means for at least 50%, in order to separate the fine-grained ore fraction. In, the separating means it should expediently be made sure that the separated fine-grained ore fraction has grain sizes of not more than 0.2 mm for at least 80 wt-%. Preferably, the ore granules withdrawn from the granulating means have grain sizes of at least 0.3 mm for at least 50 wt-%. When a finegrained fraction is sifted off from the crude ore already before drying, this crude fine ore may also be charged into the existing granulating means. The crude fine ore will usually have grain sizes of not more than 0.2 mm for at least 80 wt-%.
The ore charged into the reduction plant will usually consist of grain sizes in the range from 0.1 to 3 mm for at least 80 wt-%. This is recommended above all when the first reduction stage is designed as circulating fluidized bed, as it is the case in the known processes of the above-stated U.S. Patents. In the circulating fluidized bed, relatively high gas velocities of the fluidizing and reduction gas are employed, and the empty-conduit velocities of the gas usually lie in the range from 3 to 10 m/s. This first reduction stage as described above is expediently followed by a second reduction stage, in which the fluidized bed is held in the state of the dense phase. In this case, the empty-conduit velocities of the fluidizing and reduction gas lie in the range from 0.3 to 1 m/s.
Embodiments of the process will now be explained with reference to the drawing, which represents a flow diagram of the process.
Via line
1
, granular moist iron ore or also ore concentrate is supplied and charged into a Venturi drier
2
. The ore usually has an Fe content of at least 60 wt-%. The ore, which for instance was first passed through a not represented crushing device, has grain sizes up to not more than 10 mm, preferably not more than
6
mm. Advantageously, at least 80 wt-% of the ore of line
1
should have grain sizes of not more than 4 mm. Hot gas is supplied to the drier
2
through line
3
, so that the ore is conveyed to the top, dried and charged into a cyclone
4
through line
5
. Gas containing water and dust is withdrawn via line
4
a
and introduced into a not represented dedusting unit. Dried ore, whose temperatures usually lie in the range from 120 to 400° C., leaves the cyclone
4
through line
6
and gets into a separating means, which in the present case is designed as sifter
7
. The coarse-grained fraction leaves the sifter
7
through line
10
, and the finegrained ore fraction is supplied through line
11
to a granulator
12
. When not the entire dried ore from the cyclone
4
should be introduced into the sifter
7
, a partial quantity thereof may directly be admixed to the coarse fraction of line
10
through the bypass line
14
indicated in broken lines.
If necessary, binder such as bentonite is supplied to the granulator
12
through line
15
. Furthermore, a filter cake may be charged into the granulator through line
16
, which filter cake originates from a not represented gas cleaning unit and is rich in fine-grained iron ore. The granulator
12
known per se produces an iron ore granulate, where at least 50 wt-% of the granulate have grain sizes of at least 0.3 mm. This granulate is introduced into the drier
2
on the path
18
.
The coarse ore fraction of line
10
is heated to temperatures of 700 to 1100° C. and mostly not more than 1000° C. For this purpose a circulating fluidized bed is used, to whose reactor
20
a solid, liquid or gaseous fuel is supplied through line
21
, and air is supplied through line
22
. The hot combustion gases convey the solids upwards to a cyclone separator
23
, where the hot, dust-laden gases are supplied to the drier
2
through line
3
. The heated coarse ore leaves the cyclone
23
through line
26
and is partly recirculated to the lower part of the chamber
20
through line
27
. The remaining ore, which has been hardened as a result of heating, is supplied to the reduction plant through line
28
.
The reduction plant schematically illustrated in the drawing comprises a first reduction stage
30
, a second reduction stage
31
and a gas processing unit
32
. In the first stage
30
, a circulating fluidized bed is employed, and the second reduction stage
31
is designed as stationary fluidized bed. Details of such a reduction plant are described in the U.S. Pat. Nos. 5,527,379; 5,560,762 and 5,603,748. Hot reduction gas, which in addition to hydrogen may also contain carbon monoxide, is supplied via line
33
and as fluidizing gas partly supplied to the first stage
30
and the second stage
31
. Exhaust gas o f the second stage
31
is supplied to the first stage
30
through line
34
. The exhaust gas containing steam and dust, which leaves the first stage
30
via line
35
, is recirculated to the plant
32
for processing and partial reuse, in which plant there is also produced fresh reduction gas. The ore partly reduced in the first stage
30
is del
Beyzavi Ali
Hirsch Martin
Metallgesellschaft AG
Norris & McLaughlin & Marcus
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