Process for the synthesis of oligomeric vinylamines

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5263031, C08F 1822, C08F 2054

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active

052800776

ABSTRACT:
Vinylamide oligomers and lower molecular weight polymers are prepared by the cationic polymerization of vinylamides in the presence of a Lewis acid at a temperature between -100.degree. and 100.degree. C. The resultant vinylamide oligomers and polymers can optionally be hydrolyzed under acidic or basic conditions to form the corresponding vinylamine oligomers and polymers.

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"Solid-State Polymerization of Acrylamide and Its derivatives complexed with Lewis Acids" Orszagh et al, Journal of Polymer Science: Polymer Chemistry Edition vol. 1 No. 2 (Feb.) pp. 363-369 (1981).
Chemistry of Organic Compounds, Noller, pp. 233-235 Oct. 1, 1956.

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