Process for the synthesis of azobenzene compounds having a cyano

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260155, 260156, 260205, 260206, 260207, 2602075, 260208, C09B 4300, C09B 4340

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043158579

ABSTRACT:
A process for the synthesis of an azobenzene compound having a cyano group in one or both of the ortho positions of the diazo component radical comprising reacting the corresponding azobenzene compound having a chloro, bromo or iodo substituent in one or both of the ortho positions of the diazo component radical with a copper thiocyanate or copper thiocyanate-forming mixture of salts in the presence of an oxidizing agent (e.g., oxygen and sodium perborate), whereby the or at least one of the chloro, bromo and iodo substituents is replaced by a cyano group.

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Stedman et al., Chemical Abstracts, vol. 70, #111275h (1969).
Wilson et al., J. Am. Chem. Soc. 82, 4515-4517 (1960).
Wilson et al., J. Am. Chem. Soc. 83, 286-289 (1961).

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