Process for the start up of polymerization or copolymerization i

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 88, 526129, 526348, 5263484, 5263486, 526351, 526352, 526901, 526904, C08F 234, C08F 1000

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active

050773585

ABSTRACT:
The present invention relates to a process for the start up of polymerization or copolymerization in the gas phase by bringing the said alpha-olefins in contact under polymerization or copolymerization conditions in a fluidized bed and/or with mechanical stirring with a charge powder, in the presence of a catalyst system of the Ziegler-Natta type, this process being characterized in that the charge powder used is previously dehydrated and subjected to a treatment by bringing the said charge powder into contact with an organoaluminum compound for a period of at least five minutes, so that the polymerization or copolymerization starts up immediately after the contracting of the alpha-olefins with the charge powder in the presence of the catalyst system.

REFERENCES:
patent: 4003712 (1977-01-01), Milla
patent: 4035560 (1977-07-01), Caumartin et al.
patent: 4166167 (1979-08-01), Bye et al.
patent: 4427573 (1984-01-01), Miles et al.
patent: 4467080 (1984-08-01), Brun et al.
patent: 4564660 (1986-01-01), Williams et al.
patent: 4721763 (1988-01-01), Bailly et al.

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