Process for the separation of oligomeric materials from a cataly

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Treating with a liquid or treating in a liquid phase,...

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502 22, 502 31, 502 32, 502155, 502164, 549507, 549539, B01J 3140, B01J 3868, B01J 3848, C07D30728

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active

052388891

ABSTRACT:
Disclosed is a process for the recovery of catalyst values from mixtures of catalyst compounds and oligomeric materials. The process provides for the separation of (i) an onium iodide compound, (ii) an organotin iodide compound, or (iii) a mixture thereof from a mixture thereof in an oligomer of a .gamma.,.delta.-epoxy-alkene by the steps of (1) intimately contacting the mixture with an extraction solvent selected from hydrocarbons having about 5 to 12 carbon atoms; (2) allowing the mixture of step (1) to separate into 2 phases; and (3) recovering the extraction solvent phase containing iodide compounds (i) and (ii). The oligomer mixture of compounds (i) and/or (ii) is formed during the manufacture of 2,5-dihydrofurans by the isomerization of .gamma.,.delta.-epoxyalkenes.

REFERENCES:
patent: 2680109 (1954-06-01), Stevens et al.
patent: 4946817 (1990-08-01), Bertram et al.
patent: 5082956 (1992-01-01), Monnier et al.

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