Process for the separation of butenes and butanes by extractive

Distillation: processes – separatory – Adding material to distilland except water or steam per se – At least two materials

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203 52, 203 56, 203 58, 203 60, 203 63, 203 68, 203 69, 203 78, 203 80, 585802, 585809, 585860, 585865, 585866, 585867, B01D 340

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active

052883701

ABSTRACT:
For the separation of butenes and butanes by extractive distillation, a charge mainly containing butenes and butanes is contacted in an extractive distillation column under pressure with a first selective polar solvent, S1 (e.g., dimethyl formamide), the butanes being collected at the top. The solvent S1 containing the butenes and passing out at the bottom is mixed with a second solvent, S2, having a boiling point intermediate between that of butenes and that of the solvent S1, the mixture passing into a desorption column under pressure, where the butenes are collected at the top. The mixture of solvent S1 and S2 is separated in a purification column under atmospheric pressure, the solvent S2 passing out at the top is recycled to the desorption column, and the solvent S1 passing out at the bottom is recycled to the extractive distillation column.

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patent: 5100515 (1992-03-01), Lee et al.

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