Process for the separation of butadiene by plural stage extracti

Distillation: processes – separatory – With chemical reaction – Including step of adding catalyst or reacting material

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203 53, 203 60, 203 74, 203 77, 203 98, 203DIG19, 2606815R, B01D 340, C07C 708

Patent

active

041284577

ABSTRACT:
Butadiene is recovered from a hydrocarbon fraction containing it together with butenes and acetylene hydrocarbons by introducing said fraction into a first extractive distillation column, feeding aqueous acetonitrile into said column above the introduction point of said fraction and extracting a vapor stream containing butadiene below said introduction point; feeding said vapor stream into a second extractive distillation column, feeding aqueous acetonitrile above the introduction point of said vapor stream and recovering a vapor stream consisting essentially of butadiene at the top of said second column; and rectifying this last vapor stream to recover pure butadiene.

REFERENCES:
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patent: 3230157 (1966-01-01), Hill et al.
patent: 3436438 (1969-04-01), Takao et al.
patent: 3496070 (1970-02-01), Woerner et al.
patent: 3705204 (1972-12-01), Horie et al.
patent: 3851010 (1974-11-01), Rescalli et al.

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