Process for the selective separation of uranium, zirconium and/o

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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423 15, 423 71, C01G 4300

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active

046751661

ABSTRACT:
Process for the selective separation of uranium in carbonated aqueous solution from soluble impurities including in particular at least one of the elements zirconium and/or hafnium and/or molybdenum, thereby making it possible to produce a uraniferous liquor in a greatly improved state of purity, comprising precipitation of the zirconium and/or hafnium by introducing an alkali metal hydroxide, then separation of the zirconiferous precipitate which possibly contains hafnium and/or molybdenum from the resulting uraniferous solution with its reduced impurities content, which still possibly contains molybdenum, which is characterized in that in order to increase the removal of zirconium and/or hafnium and/or molybdenum, the uraniferous carbonated aqueous solution is treated by means of a dilute alkaline aqueous solution containing at most 17 g/l of at least one alkali metal hydroxide expressed in respect of OH.sup.-, in an amount such that the resulting pH-value is imperatively higher than 11 but is generally between 11.8 and 12.5.

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patent: 4524001 (1985-06-01), Joubert
patent: 4587109 (1986-05-01), Lyaudet et al.

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