Process for the selective production of dihydroxybenzenes

Details Process for the selective production of dihydroxybenzenes Process for the selective production of dihydroxybenzenes

1984-03-08

1986-05-20

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568741, 568798, 568803, C07C 3700

Patent

active

045903050

ABSTRACT:
The known nuclear hydroxylation of phenol or substituted phenols or phenol ethers with organic solutions of hydrogen peroxide in the presence of a catalyst is carried out in improved manner by employing both (1) a special, practically water free solution of hydrogen peroxide in an organic solvent which forms an azeotrope with water, which azeotrope boils below the boiling point of hydrogen peroxide, and (2) selenium dioxide as a catalyst. Through this, the nuclear hydroxylation is substantially simpler than previously. Besides, for the first time, it is possible to control the ortho to para ratio or the two ortho ratios to each other.

REFERENCES:
patent: 3943179 (1976-03-01), Bost
Peroxide-Chemie GmbH, pp. 4-6 and 21-23, (1981).

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