Process for the selective preparation of acetaldehyde from...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S465000

Reexamination Certificate

active

08044246

ABSTRACT:
The present invention relates to a process for the selective preparation of acetaldehyde, characterized in that acrolein and one or more ammonium salts dissolved in water are reacted continuously under high pressures and at temperatures of 300-400° C.

REFERENCES:
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Antal Jr. et al., “Catalyzed and Uncatalyzed Conversion of Cellulose Biopolymer Model Compounds to Chemical Feedstocks in Supercritical Solvents”, Energy from Biomass and Wastes, vol. 10, pp. 865-877; 1987.
Buhler et al., “Ionic Reactions and Pyrolysis of Glycerol as Competing Reaction Pathways in Near and Supercritical Water”, Journal of Supercritical Fluids, vol. 22, pp. 37-53; 2002.
Eckert et al., “Acetaldehyde”, Ullmann's Encyclopedia of Industrial Chemistry, 7. Aufl., Wiley Interscience, Online Release, 2009.
Ott et al., “Catalytic Dehydration of Glycerol in Sub and Supercritical Water: A New Chemical Process for Acrolein Production”, Green Chemistry, vol. 8, pp. 214-220; 2006.
Ott, Stoffliche Nutzung von Biomasse mit Hilfe von nah- und uberkritischem Wasser-homogenkatalysierte Dehydratisierung von Polyolen zu Aldehyden-[Material use of biomass with the aid of near-critical and supercritical water-homogeneously catalysed dehydration of polyols to give aldehydes], Thesis, TU Darmstadt, 2005.
Ramayya et al., Acid-Catalyzed Dehydration of Alcohols in Supercritical Water, Fuel, vol. 66, No. 10, pp. 1364-1371; 1987.
Watanabe et al., Acrolein Synthesis from Glycerol in Hot-Compressed Water, Bioresource Technology, vol. 98, pp. 1285-1290; 2007.

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