Process for the selective disproportionation reaction of olefins

Details Process for the selective disproportionation reaction of olefins Process for the selective disproportionation reaction of olefins

1975-08-25

1977-05-17

Davis, C.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2606832, C07C 362

Patent

active

040242013

ABSTRACT:
In the disproportionation reaction of a linear olefin such as 1-butene cocted in the presence of a supported tungsten oxide catalyst such as a tungsten oxide-silica catalyst, isomerization of the olefin is inhibited and the conversion ratio for the disproportionation reaction of the olefin is increased by conducting the reaction in the presence of an amine compound such as ammonia or n-butylamine or a halogen compound such as chloroform.

REFERENCES:
patent: 2816905 (1957-12-01), Gilbert et al.
patent: 3544647 (1970-12-01), Pennella
patent: 3546311 (1970-12-01), Heckelsberg
patent: 3637893 (1972-01-01), Singleton
patent: 3923920 (1975-02-01), Regier

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