Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component
Patent
1979-03-22
1981-02-17
Peters, G. O.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Nitrogen or nitrogenous component
423244, B01D 5300
Patent
active
042514967
ABSTRACT:
A combination process is provided in which a gaseous mixture comprising SO.sub.x and NO.sub.x is reacted with cerium oxide at a temperature ranging from about 500.degree. C. to about 700.degree. C. to form cerium oxysulfate and a gas which is at least partially desulfurized. The latter is contacted with cerium oxysulfate at a temperature ranging from about 500.degree. C. to about 700.degree. C. in the presence of ammonia at net oxidizing conditions to reduce the NO.sub.x content of the gaseous mixture. The process may be conducted in one reaction zone or in a plurality of reaction zones. The cerium oxide reactant may be regenerated by reacting cerium oxysulfate with a reducing gas such as hydrogen.
REFERENCES:
patent: 3885019 (1975-05-01), Matsushita et al.
patent: 4001375 (1977-01-01), Longo
patent: 4115516 (1978-09-01), Takami et al.
Cull Neville L.
Longo John M.
Exxon Research & Engineering Co.
Gibbons Marthe L.
Peters G. O.
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