Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing
Patent
1994-08-01
1995-07-11
Langel, Wayne
Chemistry of inorganic compounds
Phosphorus or compound thereof
Oxygen containing
C01B 2516
Patent
active
054318955
ABSTRACT:
To remove lead and cadmium from phosphoric acid, alkali solution and aqueous sulfide solution are simultaneously introduced with thorough mixing into a phosphoric acid having a P.sub.2 O.sub.5 content of up to 32% by weight, an iron content of up to 0.3% by weight and an alkali/P ratio of up to 0.30. The temperature of the phosphoric acid which is thoroughly mixed with alkali solution and sulfide solution is adjusted to temperatures of 58.degree. to 72.degree. C. with escape of the excess hydrogen sulfide. To complete the sulfide precipitation, the temperature is lowered to below 45.degree. C. Finally, the precipitated sulfides of the lead and cadmium are separated off from the phosphoric acid.
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Bennoit Horst
Damman Bernardus J.
Vermaire Dirk C.
Hoechst Aktiengesellschaft
Langel Wayne
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