Process for the removal of heavy hydrocarbonaceous co-products f

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By addition of extraneous agent – e.g. – solvent – etc.

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C07C 700

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active

054810604

ABSTRACT:
A process for the removal of trace quantities of polynuclear aromatic compounds from the vapor effluent of a hydrocarbon dehydrogenation zone containing normally gaseous olefinic hydrocarbons, trace mononuclear aromatic compounds and trace polynuclear aromatic compounds by contacting the vapor effluent of a hydrocarbon dehydrogenation zone with a lean liquid absorption stream comprising at least one mononuclear aromatic compound to absorb at least a portion of the trace mononuclear aromatic compounds and the trace polynuclear aromatic compounds to produce a rich liquid absorption stream and a gaseous olefin-containing hydrocarbon stream having a reduced concentration of mononuclear aromatic compounds and polynuclear aromatic compounds. The rich liquid absorption stream is separated to produce a stream rich in mononuclear aromatic compounds and a stream comprising polynuclear aromatic compounds. At least a portion of the stream rich in mononuclear aromatic compounds is recycled to provide at least a portion of the lean liquid absorption stream.

REFERENCES:
patent: 4430517 (1984-02-01), Imai et al.
patent: 4822948 (1989-04-01), Larue et al.

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