Process for the recovery of sodium carbonate from salt mixtures

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkali metal

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423206T, 423425, 23298, 23302T, C01D 1714, B01D 900

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active

045645086

ABSTRACT:
Mined salt mixtures comprising sodium-carbonate, -bicarbonate, -chloride, -sulfate, and -double salts, such as trona and burkeite, are leached with a bicarbonate-saturated solution and added carbon dioxide to selectively dissolve the sodium chloride, sodium sulfate and burkeite and to precipitate additional trona, leaving a leach residue consisting essentially of trona. The trona is calcined and dissolved, and the carbonate solution is purified, crystallized and dehydrated in a non-convective solar pond yielding high purity sodium carbonate monohydrate which is converted into dense soda ash. The brine solution from the leach may be treated for the recovery of a further amount of trona.

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