Process for the recovery of selenium from waste gas

Chemistry of inorganic compounds – Selenium or tellurium or compound thereof – Elemental selenium or tellurium

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423210, 4232155, 55 72, 55 97, C01B 1900

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active

039668894

ABSTRACT:
Selenium is recovered from combustion waste gas, especially the combustion waste gas evolved from glass melting furnaces by a process in which the waste gas is contacted with an absorbing solution containing an alkali metal sulfite or bisulfite, whereby metallic selenium and selenium compounds are absorbed, the temperature of the waste gas is decreased and the humidity of the waste gas is increased. The treated waste gas in then passed through a moist glass fiber filter which collects the remaining amounts of selenium from the waste gas. The absorbing solution is combined with the solution used to wash the glass fiber filter and the combined solutions are treated with an acid which reduces all of the selenium present in the solution to metallic selenium which precipitates from solution.

REFERENCES:
patent: 1271899 (1918-07-01), Howard
patent: 2349697 (1944-05-01), Bierly
patent: 2809092 (1957-10-01), Zimmerley
patent: 2889206 (1959-06-01), Hobin
patent: 2981603 (1961-04-01), Tuwiner
patent: 3179497 (1965-04-01), Yanagase
patent: 3558268 (1971-01-01), Prater
patent: 3723595 (1973-03-01), Spedden
patent: 3739549 (1973-06-01), Hevia
Weast, R. C. ed.; Handbook of Chemistry and Physics 55 Ed. C.R.C. Press, Cleveland, Ohio, p. E-5 (1974).

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