Process for the recovery of metals from used nickel/metal/rare e

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Rare earth metal

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423 215, 4231501, 423 49, 423109, 423132, 423140, 423127, 423128, 423146, 423 99, 423139, C01F 1700, B01D 1100, C01G 4900, C22B 5900

Patent

active

061104337

ABSTRACT:
The invention relates to a process for recovering metals from used nickel/hydride storage batteries, in which storage battery scrap has been mechanically comminuted and divided into at least a coarse fraction and a fine fraction capable of being treated separately from one another. The process comprises the steps of digesting and dissolving the fine fraction with a mixture of sulfuric acid and hydrogen peroxide, performing a double sulfate precipitation of the rare earths by raising the pH, performing a precipitation of the iron and of the aluminum by further raising the pH, performing a solvent extraction of other metals to separate nickel and cobalt which remain in the aqueous phase from the other metals which are extracted into the organic phase. Optionally, the nickel and the cobalt can be separated from each other and, if desired, the mixed-metal rare earth component which has been recovered can be melted together with cobalt and nickel alloy for the fabrication of new batteries.

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patent: 5728355 (1998-03-01), Asada

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