Process for the recovery of carbon dioxide from a gas stream

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

Reexamination Certificate

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Reexamination Certificate

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07601315

ABSTRACT:
A process for removing acid gas from a gas stream utilizes a low viscosity absorbent comprising a solution of at least one selected amine. The absorbent may include (1) at least one polyamine in the absence of an effective amount of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, wherein the polyamine has at least one primary amine functionality having a pKa of <10.0 at 25° C. and wherein the feed gas stream has an SO2 concentration less than 5 ppm vol.; or (2) a polyamine in the absence of an effective amount of tertiary amine functionalities having a pKa sufficient to neutralize carbamic acid, wherein the polyamine has at least one secondary amine functionality having a pKa for each sorbing nitrogen of <10.0 at 25° C. The polyamines may include diethylenetriamine (DETA), triethylenetetramine (TETA) and tetraethylenepentamine (TEPA) or mixtures thereof.

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Idem et al, Pilot Plant /studies of the CO2 Capture Performance of Aqueous MEA land MEA/MDEA Sovents at the University of Regina CO2 Capture Technology Development Plant and the Boundry Dam CO2 Capture Demonstration Plant, Ind. Eng. Chem. Res. 2006, 45, 2414-2420.

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