Process for the recovery in the form of tetravalent fluoride of

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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423259, C01G 4306

Patent

active

047584114

ABSTRACT:
A process for the recovery of uranium which has been extracted from phosphate-bearing solutions by means of an organic solvent and which is re-extracted from said solvent by means of hydrofluoric acid is disclosed.
The process is characterized in that sodium ions are introduced into the solution of hydrofluoric acid, while aluminum and magnesium ions may also be added to the sodium ions. That solution may be produced by recycling of a fraction of the suspension of fluoride from the re-extraction step, after having separated the solvent, and to which a make-up of sodium, aluminum and magnesium ions and hydrofluoric acid was added.

REFERENCES:
patent: 2830872 (1958-04-01), McCullough
patent: 2866680 (1958-12-01), Long
patent: 2869979 (1959-01-01), Grinstead
patent: 2873165 (1959-02-01), Bailes et al.
patent: 2882123 (1959-04-01), Long
patent: 3004051 (1961-10-01), Hillyer
patent: 3030175 (1962-04-01), Magner et al.
patent: 4374807 (1983-02-01), Ishimi
patent: 4478804 (1984-10-01), Watanabe et al.
D. A. Ellis, "The Recovery of Uranium from Industrial Phosphoric Acids by Solvent Extraction", report Dow-81, Contract No. AT-30-1-GEN-236, pp. 47-49 (Jul. 14, 1952).
B. F. Greek, ass't Ed., "Uranium Recovery from Wet Process Phosphoric Acid", Ind. and Engineering Chem., vol. 49, #4, pp. 628-638, Apr. 1957.
Berkman, S. et al., Emulsions and Foams, N.Y., Reinhold Pub. Corp., 1941, pp. 285-286.

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