Process for the racemization of optically active aminoacids

Details Process for the racemization of optically active aminoacids Process for the racemization of optically active aminoacids

1984-09-25

1987-01-20

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

562443, 562444, 562445, 562446, 562450, 562553, 562557, 562559, 562560, C07B 5500

Patent

active

046380868

ABSTRACT:
The racemization of optically active aminoacids (including their N-acyl derivatives) by heating with carboxylic acids takes place particularly readily with carboxylic acids of low volatility. Only catalytic quantities of acid are needed; it is advantageous to use equimolar quantities or an excess, which serves as a diluent. A reaction mixture from an enzymatic racemate resolution can be heated directly for the purpose of racemization, after separation of the L-aminoacid and the water.

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