Process for the quantitative determination of electrochemically

Electrolysis: processes – compositions used therein – and methods – Electrolytic analysis or testing – For ph

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204412, 204403, 204415, 204406, 204409, 436 52, 436124, 436149, 436150, G01N 2726

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active

055037208

ABSTRACT:
A process for the quantitative determination of oxidizing and reducing substances is described, also mixed with chemically similarly reacting substances, particularly peracetic acid mixed with further substances such as hydrogen peroxide (H.sub.2 O.sub.2) and/or acetic acid by means of per se known potentiostatic amperometry, in which the determination takes place with a test electrode voltage, which, independently of the prevailing reaction mechanism, is below the diffusion limiting current range between the no-load voltage and the flex point of the current density-voltage curve. The peracetic acid determination takes place at a current density of <5%, preferably <1% of the limiting current density.

REFERENCES:
patent: 5395493 (1995-03-01), Pinkowski

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