Process for the purification of Ropinirole hydrochloride

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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Reexamination Certificate

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07968731

ABSTRACT:
An improved process is described for the purification of ropinirole hydrochloride. The process includes (i) dissolving ropinirole hydrochloride in water; (ii) treating the solution obtained in step (i) with sodium dithionate and charcoal; (iii) treating the filtrate obtained in step (ii) with water immiscible solvent and base and isolating the free base; and (iv) treating the free base obtained in step (iii) with ethanolic HCl to give ropinirole hydrochloride.

REFERENCES:
patent: 4452808 (1984-06-01), Gallagher
patent: 4997954 (1991-03-01), Fortunak
patent: 2010/0179332 (2010-07-01), Deshpande et al.
patent: WO 2005080333 (2005-09-01), None
patent: WO 2005105741 (2005-11-01), None
patent: WO 2005105741 (2005-11-01), None
Gallagher et al., “4-[2-(Di-n-propylamino)ethyl]-2(3H)-indolone: A Prejunctional Dopamine Receptor Agonist”, J. Med. Chem., pp. 1533-1536, (1985).
Demarinis et al., “Synthesis and in Vitro Evaluation of 4-(2-Aminoethyl)-2(3H)-indolones and Related Compounds as Peripheral Prejunctional Dopamine Receptor Agonists”, J.Med.Chem., pp. 939-947, (1986).

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