Process for the purification of medium-chain olefins

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By addition of extraneous agent – e.g. – solvent – etc.

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585520, 585664, 585666, 585667, 585670, 585800, 585851, 585852, C07C 700, C07C 748

Patent

active

057896461

ABSTRACT:
Medium-chain olefins containing as impurities 2-alkyl substituted isomers having a close boiling point are purified by (i) passing over a solid acid catalyst under mild conditions to selectively double-bond isomerise said impurities, and (ii) separating said isomerised olefins by distillation.

REFERENCES:
patent: 2421229 (1947-05-01), Zimmerman
patent: 2428516 (1947-10-01), Drenna
patent: 3920765 (1975-11-01), Frech et al.
patent: 4527004 (1985-07-01), Sweeney
patent: 4547780 (1985-10-01), Wilson
patent: 5132484 (1992-07-01), Gajda
patent: 5237120 (1993-08-01), Haag et al.

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