Process for the purification of an oxidation off gas with energy

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Organic component

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60 3902, 95237, 560 77, 562414, F02C 320, C07C 5116

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active

056141599

ABSTRACT:
In the purification of an off-gas stream originating from a process of oxidizing a liquid mixture of para-xylene with methyl para-toluate with an oxygen-containing gas under pressure, the off-gas being contaminated with at least one of an aliphatic and an aromatic impurity, which comprises expanding the off-gas stream in an expansion turbine for generating mechanical or electrical energy so as to obtain an at least partial recovery of the energy contained in the off-gas, the improvement comprising subjecting the off-gas to at least one absorption step under pressure to remove at least one component from the off-gas and subjecting the resultant off-gas stream to combustion under a pressure of more than 3 bar prior to expanding the off-gas stream in the expansion turbine.

REFERENCES:
patent: 3603085 (1971-09-01), Parmegiani et al.
patent: 3989600 (1976-11-01), Takahashi et al.
patent: 4102983 (1978-07-01), Yamase et al.
patent: 4172209 (1979-10-01), Vora
patent: 4464477 (1984-08-01), Buenger et al.
patent: 4642369 (1987-02-01), Modic et al.
patent: 4642377 (1987-02-01), Modic et al.
Official Translation of Nozaki, K., et al., Japanese Kokai 54-148,178, published Nov. 20, 1979.

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