Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1984-06-13
1986-06-03
Helfin, Bernard
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
560 25, 560 27, 560 28, 560 30, 560 32, 560 9, 560 13, 560115, 560157, 560158, 560162, 560163, 544 37, C07C125065, C07C125073, C07C125067, C07C125075
Patent
active
045931160
ABSTRACT:
Urethanes are made by reacting an organic nitro compound with an organic compound containing at least one hydroxyl group in the presence of carbon monoxide, hydrogen and a catalyst system. The carbon monoxide and hydrogen are used in quantities such that the molar ratio of CO to H.sub.2 is from 0.3:1 to 3:1. The catalyst system is made up of at least one noble metal or compound of a noble metal from Group VIIIB of the Periodic System of Elements, at least one organic nitrogen base and a co-catalyst combination of iron or copper oxidic or hydroxidic compound and a chloride compound. The product urethanes are useful in the production of isocyanates and pesticides.
REFERENCES:
patent: 4219661 (1980-08-01), Becker et al.
patent: 4262130 (1981-04-01), Becker et al.
patent: 4339592 (1982-07-01), Becker et al.
Onoda et al, Chem. Abs., vol. 93 (1980) 167,981c.
Asahi, Chem. Abs., vol. 98 (1983) 178,991k.
Patent Abstracts of Japan, Band 3, Nr. 138, Nov. 16, 1979.
Becker Robert
Grolig Johann
Stammann Gunter
Waldmann Helmut
Bayer Aktiengesellschaft
Gil Joseph C.
Harsh Gene
Helfin Bernard
Whalen Lyndanne M.
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