Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Patent
1984-08-13
1987-06-02
Hines, Robert V.
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
564 70, 564 71, C07C12602
Patent
active
046705880
ABSTRACT:
A process for the synthesis of urea from ammonia and carbon dioxide in which high yield reaction and optimal reactor heat balance control are achieved at the same time by using two reaction zones, where two different NH.sub.3 /CO.sub.2 molar ratios are maintained, and by treating the effluent from the second reaction zone in a separation treatment in two steps in series; the reactant gas stream discharged from the second treatment step is recycled, after partial condensation, to the first reaction zone, while at least part of the gas stream discharged from the first treatment step is recycled directly to the second reaction zone, the gas stream from both the first and second treatment step being so controlled as to obtain optimal NH.sub.3 /CO.sub.2 ratios and optimal reaction temperatures in the two reaction zones.
REFERENCES:
patent: 3607938 (1971-09-01), Braun
patent: 3984469 (1976-10-01), Guadalupi et al.
patent: 4066693 (1978-01-01), Venderbos
patent: 4137262 (1979-01-01), Gaudalupi et al.
patent: 4208347 (1980-01-01), Pagani
patent: 4314077 (1952-02-01), Zardi et al.
Ammonia Casle S.A.
Hines Robert V.
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