Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1993-01-06
1995-06-20
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
562485, 562487, 568858, 568868, C07C 51487
Patent
active
054262178
ABSTRACT:
A process for the production of terephthalic acid comprises subjecting polyalkylene terephthalate to hydrolysis using a ratio of water to polyalkylene terephthalate in the mixture prior to heating and carrying out the reaction under conditions such that, at the reaction temperature, a significant proportion of the terephthalic acid produced is in the solid phase. The degree of recrystallization necessary to recover the terephthalic acid produced is thereby reduced. The reaction can with advantage be carried out with alkylene glycol present in the mixture prior to hydrolysis.
REFERENCES:
patent: 4578510 (1986-03-01), Doerr
patent: 4620032 (1986-10-01), Doerr
patent: 5095145 (1992-03-01), Rosen
Harvie James L.
Royall David J.
Barts Samuel
Dees Jos,e G.
Imperial Chemical Industries PLC
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