Process for the production of tertiary olefin(s) by decompositio

Details Process for the production of tertiary olefin(s) by decompositio Process for the production of tertiary olefin(s) by decompositio

1997-04-08

2000-02-22

Yildirim, Bekir L.

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

From nonhydrocarbon feed

585639, C07C 120

Patent

active

060282398

ABSTRACT:
The invention concerns a process for the decomposition of tertiary alkyl ether(s), preferably selected from the group formed by ETBE, MTBE, TAME and ETAE, for the production of generally high purity tertiary olefin(s), preferably isobutene and isoamylenes, using a catalyst comprising at least one inorganic solid, for example a polysiloxane type solid, grafted with at least one alkyl sulphonic acid, aryl sulphonic acid or alkylaryl sulphonic acid type organic group.

REFERENCES:
patent: 4656016 (1987-04-01), Taramasso et al.
patent: 5095164 (1992-03-01), Gabel et al.
patent: 5354831 (1994-10-01), Panster et al.

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